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METAL RECOVERY TECHNOLOGIES

ZINCEX TECHNOLOGY

The ZINCEX® technology offers a robust, reliable, and flexible alternative for the beneficiation of zinc minerals and concentrates that are difficult to process by conventional methods. This technology is the first industrial reference for zinc production via hydrometallurgical route using solvent extraction.

A clear example of the versatility of this technology is its successful implementation for a wide variety of raw materials (including oxidised ore, waelz oxides, discharged batteries etc) in Spain, Nambia, Japan, Italy and the United States and with treatment capacities ranging from 2,000 tons of zinc per year to 150,000 tons.
ZINCEX® technology consists of the following stages:

LEACHING:

This process is done in an acid medium with the aim of obtaining a solution with the zinc present in the starting material.

SOLVENT EXTRACTION

The solvent extraction stage purifies and concentrates the zinc solution acting as a barrier to impurities towards the subsequent stages of the technology.

ELECTROLYSIS:

Electrolysis: The the electrolysis circuit has the aim of electrophoretically depositing highly pure metallic zinc sheets (SHG quality) by reducing the zinc dissolved in the charged electrolyte, achieved by applying an electric current.

The key to ZINCEX®'s success lies in its ability to treat zinc-loaded solutions across a wide range, from 1 g/l to 160 g/l of zinc, making it ideal for combination in multiple projects and applications. Additionally, it can produce an electrolyte of the highest purity by setting insurmountable barriers not only to typical impurities such as nickel, cobalt, cadmium, etc., but also to other elements like calcium, magnesium, manganese, chlorine, and fluorine, which have a detrimental effect on zinc electrolysis.

The following figure compares the behavior of the main impurities in the ZINCEX® process and in the RLE (Roasting Leaching Electrowinning) technology:

CONVENTIONAL PROCESS Roasting, Leaching, Electrowinning

NOTE: The dotted lines indicate ppm or ppb.

ZINCEX® PROCESS

NOTE: The dotted lines indicate ppm or ppb.

KEY PROCESS REFERENCES
Rosh Pinah – Namibia Vedanta 150.000 t/yr Oxidised zinc ores Greenfield
Akita – Japan Dowa 20.000 t/yr Waelz oxides Brownfield
Sardinia – Italy Glencore 52.500 t/yr Waelz oxides Brownfield
Mooresboro – EEUU American Zinc Recycling 135.000 t/yr Secondary zinc oxides such as Waelz Oxide and Skimmings. Greenfield

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TR PROPRIETARY TECHNOLOGY DIVISION
Cl. Sierra Nevada 16
Pol. Ind. San Fernando de Henares
28830 San Fernando de Henares,
Madrid – Spain
Tel: +34 914 09 89 55
Email: tr@tecnicasreunidas.es

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